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Determinação das constantes de estabilidade dos complexos formados entre os aminoácidos cisteína, N-acetilcisteína e lisina com chumbo em solução aquosa
(Universidade Federal de Santa Maria, 2011-01-18)
In this study we investigated the interaction between lead and the amino acid cysteine, lysine and N-acetylcysteine by testing long-term contact with ion exchanger resins and also the determination of stability constants. ...
Determinação de resíduos de compostos orgânicos em água por microextração líquido-líquido dispersiva (DLLME) E GC-(TQ)MS/MS
(Universidade Federal de Santa Maria, 2010-11-29)
The use of chemicals, which generates a lot off benefits, is responsible for the contamination of soil, water and foods. The concern about contamination of surface
and ground water systems by pesticides has grown in ...
Síntese e avaliação de arranjos supramoleculares de triazenos monocatenados e complexos com os cátions Co3+, Cu2+, Ag+ e Au+
(Universidade Federal de Santa Maria, 2010-08-31)
Triazenes ligands substituted by terminal aryl groups in the diazoamine chain [ N=N N(H) ] containing NO2 group substituted in different position and ortho C(O)NH2 on aryl ring was evaluated on the occurrence of intermolecular ...
Estudo do comportamento químico de heterociclos trifluormetil substituídos em reações com DAST
(Universidade Federal de Santa Maria, 2011-03-01)
This work describes the study of the chemical behavior of trifluoromethyl substituted heterocycles as 1H-pyrazoles, 2-pyrazolines, 2H-cromenones and isoxazolines in reactions with DAST, with the aim of evaluating possible ...
Validação e aplicação de método empregando QuEChERS modificado e GC-ECD para determinação de resíduos de pesticidas em grão e casca de arroz
(Universidade Federal de Santa Maria, 2010-08-12)
The current agriculture is characterized by the use of new technologies and equipment, the increased number of agronomic research and the use of a variety of inputs such as pesticides and fertilizers. All this is directly ...
Síntese regiosseletiva de Dideoxinucleosídeos e 3(5)-Trifluormetil-1H-pirazóis de interesse farmacológico
(Universidade Federal de Santa Maria, 2015-05-29)
This work reports the synthesis of a series of 29 new 1-(3-aryl-4,5-dihydroisoxazol-5-yl)methyl-4-trihalomethylpyrimidin-2(1H)-ones which have high pharmacological interest, since they are similar to natural and synthetic ...
Aplicação de 5-bromo-1,1,1-trifluor-4-metoxipent-3-en-2-ona na síntese de pirróis, pirazóis, pirimidinas e 1,2,3-triazóis
(Universidade Federal de Santa Maria, 2015-10-30)
This thesis reports the synthesis of various series of trifluoromethyl substituted nitrogenated heterocycles, such as pyrroles, pyrazoles, pyrimidines and 1,2,3-triazoles, exploiting the synthetic versatility of ...
Síntese de copolímeros em bloco por reações one-pot com processos RAFT e ROP simultâneos
(Universidade Federal de Santa Maria, 2016-02-04)
The present work describes a methodology of controlled synthesis of block copolymers by one-pot reactions involving simultaneous RAFT and ROP processes mediated by a bifunctional compound which acts as a chain transfer ...
HPAs em águas superficiais e efluente hospitalar: degradação por PAOs e desenvolvimento de métodos para determinação e identificação de subprodutos
(Universidade Federal de Santa Maria, 2016-02-26)
In this study, was optimization an analytical method for identification and quantification method of Polycyclic Aromatic Hydrocarbons (PAHs) in surface water and hospital effluent samples. High Performance Liquid Chromatography ...
Determinação de POPs e agrotóxicos em leite materno empregando cromatografia a gás acoplada à espectrometria de massas com ionização química negativa (GC-NCI-MS)
(Universidade Federal de Santa Maria, 2016-03-31)
The Stockholm Convention was the first global attitude trying to preserve human health and the environment of the indiscriminate use of persistent organic pollutants (POPs), especially pesticides, which are characterized ...