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Sistemas bidimensionais formados por silício e germânio: um estudo de primeiros princípios
(Universidade Federal de Santa Maria, 2015-07-14)
First principles calculations within the density functional theory have been used to
study the main structural, energetic, electronic, and optical properties of hydrogenated Si
and Ge in the 2D structures (silicane and ...
Transição semicondutor-metal em nanocristais de VO2 termoeletricamente ativada
(Universidade Federal de Santa Maria, 2015-05-26)
In this thesis, structural and electrical characteristics are investigated around the thermally
triggered semiconductor to metal transition in VO2 thin films. The films, the metallics
electrodes, as well as SiO2 buffer ...
Síntese regiosseletiva de Dideoxinucleosídeos e 3(5)-Trifluormetil-1H-pirazóis de interesse farmacológico
(Universidade Federal de Santa Maria, 2015-05-29)
This work reports the synthesis of a series of 29 new 1-(3-aryl-4,5-dihydroisoxazol-5-yl)methyl-4-trihalomethylpyrimidin-2(1H)-ones which have high pharmacological interest, since they are similar to natural and synthetic ...
Aplicação de 5-bromo-1,1,1-trifluor-4-metoxipent-3-en-2-ona na síntese de pirróis, pirazóis, pirimidinas e 1,2,3-triazóis
(Universidade Federal de Santa Maria, 2015-10-30)
This thesis reports the synthesis of various series of trifluoromethyl substituted nitrogenated heterocycles, such as pyrroles, pyrazoles, pyrimidines and 1,2,3-triazoles, exploiting the synthetic versatility of ...
Síntese e bioatividade de sistemas pirazolil-piridínicos poli-heterocíclicos trialometil substituídos
(Universidade Federal de Santa Maria, 2015-03-02)
This thesis describes the studies carried out using the reagent 6-
hydrazinonicotinic hydrazide for the synthesis of new trihalomethylated pyrazolylpyridine
systems using the 4-alkoxy-4-alkyl(aryl/heteroaryl-1,1,1-trihal ...
Síntese de heterociclos: 2-alquil/arilcalcogeno-n-(4-aril-1,3-tiazol-2-il)acetamidas e (s)-n-(1-(3-aril-1,2,4-oxadiazol-5-il)alquil)-2-(calcogenofenil) acetamidas derivados de organocalcogênios
(Universidade Federal de Santa Maria, 2015-03-27)
In the present work, a series of 2-alkyl/arylchalcogenide-N-(4-aryl-1,3-thiazol-2-yl)acetamide was prepared via addition of aryl or alkyl chalcogenides. This methodology allowed the preparation of new derivatives of ...
Compostos de coordenação derivados do disseleneto e disselenoéteres de bis(2-piridina) síntese, caracterização e aplicações
(Universidade Federal de Santa Maria, 2015-03-06)
This work describes the synthesis and characterization of nineteen compounds derivative of diselenide and diselenoethers of bis(2-pyridyl) with metals of different degree of hardness. Among the nineteen obtained complex, ...
Síntese de novos isoxazóis e pirazóis a partir de derivados 1,3-diíno indólicos
(Universidade Federal de Santa Maria, 2015-04-06)
In this work it describe the synthesis and characterization of new 1,3-diynes indole derivatives, the 1,6-bis(1H-indol-1-yl)hexa-2,4-diynes (6 examples) and unsymmetrical 1-(5-arylpenta-2,4-diynyl)-1H-indoles (6 examples), ...
Avaliação da calibração em LA-ICP-MS usando papel filtro para análise de plantas
(Universidade Federal de Santa Maria, 2015-01-13)
In this work, a new calibration strategy was investigated for the determination of As, Ba, Cd,
Ce, Co, Cr, Cu, La, Mn, Ni, Pb, Se, Sr, Tl, V and Zn in medicinal plants by laser ablation and
inductively coupled plasma mass ...
Síntese e caracterização de novos compostos envolvendo Índio e Calcogênios
(Universidade Federal de Santa Maria, 2015-07-15)
This work is composed of two parts. The first one describes the synthesis of organometallic compounds derived from Br2InCH2Br and dichalcogenoether ligands, RE(CH2)nER (E = Se, Te; n = 1, 3; R = Ph, p-C6H4NMe2), compounds ...