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Compostos de coordenação derivados do disseleneto e disselenoéteres de bis(2-piridina) síntese, caracterização e aplicações
(Universidade Federal de Santa Maria, 2015-03-06)
This work describes the synthesis and characterization of nineteen compounds derivative of diselenide and diselenoethers of bis(2-pyridyl) with metals of different degree of hardness. Among the nineteen obtained complex, ...
Síntese de novos isoxazóis e pirazóis a partir de derivados 1,3-diíno indólicos
(Universidade Federal de Santa Maria, 2015-04-06)
In this work it describe the synthesis and characterization of new 1,3-diynes indole derivatives, the 1,6-bis(1H-indol-1-yl)hexa-2,4-diynes (6 examples) and unsymmetrical 1-(5-arylpenta-2,4-diynyl)-1H-indoles (6 examples), ...
Avaliação da calibração em LA-ICP-MS usando papel filtro para análise de plantas
(Universidade Federal de Santa Maria, 2015-01-13)
In this work, a new calibration strategy was investigated for the determination of As, Ba, Cd,
Ce, Co, Cr, Cu, La, Mn, Ni, Pb, Se, Sr, Tl, V and Zn in medicinal plants by laser ablation and
inductively coupled plasma mass ...
Estudo comparativo da bioatividade de compostos fenólicos em plantas medicinais
(Universidade Federal de Santa Maria, 2013-09-25)
Phenolic compounds are secondary metabolites, widely distributed in the plant
kingdom, which present antiinflamatory, antibacterial, antiviral, antialergical and
antitumoral activities, in addition to antioxidant activities. ...
Síntese e caracterização de novos compostos envolvendo Índio e Calcogênios
(Universidade Federal de Santa Maria, 2015-07-15)
This work is composed of two parts. The first one describes the synthesis of organometallic compounds derived from Br2InCH2Br and dichalcogenoether ligands, RE(CH2)nER (E = Se, Te; n = 1, 3; R = Ph, p-C6H4NMe2), compounds ...
Síntese de pirazolo[1,5-a]pirimidinas e fluorfenilpirazóis trifluormetilados em ultrassom e síntese e aplicação de [2]rotaxanos
(Universidade Federal de Santa Maria, 2014-02-14)
This work presents the synthesis of three series of trifluoromethylated heterocycles
by using ultrasound irradiation, nomely pyrazolo[1,5-a]pyrimidines, 2,4-
difluorophenylpyrazoles and pentafluorophenylpyrazoles. The ...
Síntese de 4-organocalcogenil-1h-isocromen-1-iminas e 3-(alquil calcogenoil-2-benzofenil[b]selenofeno[2,3-d] calcogenofenos via reações de ciclização mediadas por sais de ferro
(Universidade Federal de Santa Maria, 2016-08-03)
In this work we developed the efficient and selective heterocyclic product synthesis
using as electrophilic agent a ferric chloride combinated with diorganyl
dichalcogenides under mild conditions. In the first part of this ...
Síntese, análise estrutural e avaliação da atividade catalítica mimética da superóxido dismutase e peroxidases de complexos derivados do piridoxal e cobre
(Universidade Federal de Santa Maria, 2016-03-31)
This work presents the synthesis and characterization of copper complexes
that mimic the activity of the superoxide dismutase enzyme, which operates in the
elimination of reactive oxygen species or in the activation of ...
Reações de β-enaminodicetonas com ncn dinucleófilos: obtenção de pirimidinas e sistemas heterocíclicos fundidos
(Universidade Federal de Santa Maria, 2016-08-26)
In this study the reactivity of β-enamino diketones [RC(O)C(=CHNMe2)C(O)CO2Et, R = C6H5, 4-Me-C6H4, 4-MeO-C6H4, 4-F-C6H4, 4-Br-C6H4, 4-NO2-C6H4, tien-2-il] with NCN bisnucleophiles as amidine and guanidine was investigated. ...
Polímeros fluorados anfifílicos para aplicação em diagnósticos por imagens de ressonância magnética
(Universidade Federal de Santa Maria, 2014-12-17)
The goal of this study is to present kinetic studies of (co)polymerization as well
as the synthesis and characterization of amphiphilic copolymers with a fluorinated
segment. Copolymers were obtained by RAFT (co)polymerizations ...