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Desenvolvimento de método simples e rápido para determinação multiclasse de resíduos de medicamentos veterinários em rim, fígado e músculo bovino por UHPLC-MS/MS
(Universidade Federal de Santa Maria, 2017-03-10)
In food security area, the application of good agricultural practices is a growing concern for public health in the Brazilian domestic market and for the competitiveness countries in the external market. To ensure safety ...
Máquinas moleculares sintéticas: tetraalquil[2]rotaxanos como modelo no estudo de interações intramoleculares e intermoleculares
(Universidade Federal de Santa Maria, 2017-07-26)
This work presents the study of intramolecular and intermolecular interactions in tetraalkylsuccinamide[2]rotaxanes. These compounds have two submolecular components interlocked being obtained through a supramolecular ...
Determinação de hidrocarbonetos policíclicos aromáticos, níquel e vanádio em frações ácidas, básicas e neutras de asfaltos virgens e envelhecidos
(Universidade Federal de Santa Maria, 2017-08-15)
Asphalt cement (AC) is a dark-colored binder material, consisting of a mixture of naturally occurring petroleum hydrocarbons or obtained from distillation, which contains small fractions of sulfur, nitrogen, oxygen and ...
Estrutura supramolecular de cristais multicomponentes derivados do ácido salicílico e do ibuprofeno
(Universidade Federal de Santa Maria, 2017-03-17)
This work presents the study of multicomponent crystals formed by salicylic acid (AS) with 1,2-Phenylenediamine (FEN) and 3-Amino-1,2-4-1H-triazole (TRIA) as amines; and rac-ibuprofen (IBU) with 3-amino-5-methyl-1H-pyrazole ...
Síntese e caracterização de complexos de rênio e tecnécio contendo ligantes arilcalcogenolatos (Se, Te)
(Universidade Federal de Santa Maria, 2017-12-06)
Rhenium and technetium coordination chemistry containing arylthiolate ligands are long known in the
literature. However, there is a limited understanding regarding the correlates containing heavier
chalcogens (Se and ...
Estudo molecular e supramolecular de complexos triazenidos com metais de transição: uma abordagem voltada à engenharia de cristais
(Universidade Federal de Santa Maria, 2017-09-15)
This work shows the synthesis of unpublished Zn(II), Cd(II) and Pd(II) complexes with
bis-cated triazene molecules, including macrocycles. Together these compounds, a series of
symmetrical ortho-halogenated single-catenad ...
Obtenção e estudo da reatividade de ciano-acrilatos de etila e compostos relacionados com ênfase na síntese de N- e O-heterociclos
(Universidade Federal de Santa Maria, 2017-09-19)
This work reports the results of the reactivity study of the ethyl cyano-acrylates (3), obtained from the Horner-Wadsworth-Emmons (HWE) olefination reaction applied to α,β-unsaturated ketones (1) with diethyl (cyanomethy ...
Determinação multirresíduo de agrotóxicos em milho empregando método QuEChERS modificado e LC-MS/MS
(Universidade Federal de Santa Maria, 2017-09-22)
Corn is a cereal used in human and animal food, and moreover, as a source of raw material for other by-products, acquiring global importance. By presenting a distinct centesimal composition when compared with others cereals, ...
Síntese de pirrolocumarinas via nitroestirenos e de novos selenetos derivados da cumarina
(Universidade Federal de Santa Maria, 2017-03-08)
This work describes the synthesis of pyrrolo[3,2-c]coumarins from 4-aminophenylcoumarins and nitrostyrenes (17 examples), which were obtained in yelds between 6 and 76 % in a reaction catalised by PTSA.H2O and under ...
Agrotóxicos em vinho: avaliação do método QuEChERS e da microextração líquido-líquido dispersiva na determinação multirresíduo por UHPLC-MS/MS
(Universidade Federal de Santa Maria, 2017-03-10)
The widespread use of pesticides in agriculture has brought many benefits such as, increasing quantity and quality of crops grown. However, there is a concern regarding to the presence of pesticide residues in the consumed ...